Chlorido{4-ethyl-1-[1-(pyrazin-2-yl)ethylidene]thiosemicabazidato-κS}bis(triphenylphosphane-κP)silver(I)
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چکیده
The title compound, [Ag(C9H13N5S)Cl(C18H15P)2], crystallizes with four independent mol-ecules in the asymmetric unit, in each of which the Ag atom is in a distorted tetra-hedral coordination, defined by the chloride ligand, the S atom of the neutral ligand and two P atoms derived from the triphenyl phosphine ligands. The thio-semicarbazone acts as a monodentate ligand through its thione S atom. An intra-molecular N-H⋯Cl hydrogen bond occurs in two of the independent mol-ecules. In the crystal, the mol-ecules are assembled through N-H⋯Cl hydrogen bonds, forming chains along [101].
منابع مشابه
Iodido[1-(propan-2-ylidene)thiosemicarbazide-κS]bis(triphenylphosphane-κP)copper(I)
In the mononuclear title complex, [CuI(C(4)H(9)N(3)S)(C(18)H(15)P)(2)], the Cu(I) ion displays a distorted tetra-hedral coordination geometry involving two P atoms of two triphenyl-phosphane mol-ecules, one S atom of a 1-(propan-2-yl-idene)thio-semicarbazide mol-ecule and one iodide ion. In the crystal, C-H⋯π inter-actions [C-H⋯centroid distances = 3.443 (3) and 3.788 (3) Å] and N-H⋯S hydrogen ...
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